Oxygen → HCID 21546943, compound

HRID 1605487Notes

Reaction equation

HRID 1605487 reaction equation
C1CCCCC1.S(=O)(=O)(O)O.O=O.[N+:14]([CH:17]1[CH2:22][CH2:21][CH2:20][CH2:19][CH:18]1[OH:23])([O-:16])=[O:15].[N+:24](C1CCCCC1)([O-:26])=[O:25]>C(Cl)(Cl)(Cl)Cl>[N+:24]([O-:26])([O:23][CH:18]1[CH2:19][CH2:20][CH2:21][CH2:22][CH:17]1[N+:14]([O-:16])=[O:15])=[O:25]

Participants

7

Reactant 5

HCID 977OxygenHCID 1118Sulfuric AcidHCID 8078CyclohexaneHCID 14285NitrocyclohexaneHCID 2779672-Nitrocyclohexan-1-ol

Product 1

HCID 21546943HCID 21546943, compoundYield 30%

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

A solution of 4.4 grams (50 mmoles) of cyclohexane in 50 milliliters of carbon tetrachloride containing 1 milliliter of concentrated sulfuric acid was treated with 6.9 grams of N2O4 and 21 grams of oxygen at about 5°C. Analysis of the isolated product (7.3 grams) showed it consisted of a mixture of 2-nitrocyclohexyl nitrate (30 percent yield), 2-nitrocyclohexanol, nitrocyclohexane and carboxylic acids.

Sources & evidence

ORD record
ord-2e17e7bd23004afdb12286fb77d690d4
Source dataset
uspto-grants-1976_04
Patent number
US03950385

Reaction notes

Loading…