HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → HCID 21546943, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | Cyclohexane | HCID 8078 | — |
| Reactant | Nitrocyclohexane | HCID 14285 | — |
| Reactant | 2-Nitrocyclohexan-1-ol | HCID 277967 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 21546943 | HCID 21546943 | 30% |
Reaction Steps
A solution of 4.4 grams (50 mmoles) of cyclohexane in 50 milliliters of carbon tetrachloride containing 1 milliliter of concentrated sulfuric acid was treated with 6.9 grams of N2O4 and 21 grams of oxygen at about 5°C. Analysis of the isolated product (7.3 grams) showed it consisted of a mixture of 2-nitrocyclohexyl nitrate (30 percent yield), 2-nitrocyclohexanol, nitrocyclohexane and carboxylic acids.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03950385 |
| Source dataset | uspto-grants-1976_04 |
| ORD ID | ord-2e17e7bd23004afdb12286fb77d690d4 |
| Source note | uspto-grants-1976_04 |