Water → HCID 22760978, compound

HRID 1605637Notes

Reaction equation

HRID 1605637 reaction equation
[O:1]=[C:2]1[CH2:20][CH2:19][C:5]2[C:6]3[CH:18]=[CH:17][CH:16]=[CH:15][C:7]=3[O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[C:4]=2[CH2:3]1.[H-].[Al+3].[Li+].[H-].[H-].[H-].O>CCOCC>[OH:1][CH:2]1[CH2:20][CH2:19][C:5]2[C:6]3[CH:18]=[CH:17][CH:16]=[CH:15][C:7]=3[O:8][C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=3[C:4]=2[CH2:3]1

Participants

5

Reactant 3

HCID 962WaterHCID 21226445Aluminium lithium hydrideHCID 22760937HCID 22760937, compound

Product 1

HCID 22760978HCID 22760978, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

6.2 g of 2-keto-1,2,3,4-tetrahydro-tribenzo(b,d,f)-oxepine are added to a suspension of 3.7 g of lithiumaluminiumhydride in 300 ml of dry ether. After refluxing for 2 hours 14.8 ml of water are added carefully. The suspension obtained is filtered off and after that the filtrate is dried and evaporated to dryness.

Workup

  1. additionare added carefully
  2. customThe suspension obtained
  3. filtrationis filtered off
  4. customafter that the filtrate is dried
  5. customevaporated to dryness

Sources & evidence

ORD record
ord-40a252d0c60f46e7984a0e90e2e9ff6d
Source dataset
uspto-grants-1976_04
Patent number
US03950425

Reaction notes

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