Sodium Hydroxide → HCID 21542730, compound

HRID 1606393Notes

Reaction equation

HRID 1606393 reaction equation
[C:1](Cl)(=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:9](Cl)=[O:10].Cl[C:15](Cl)=[C:16](Cl)Cl.[CH3:20][NH:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27].[OH-].[Na+]>O>[CH3:20][N:21]([CH2:22][CH2:23][CH2:24][CH2:25][CH2:15][CH3:16])[C:1](=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][C:9]([N:21]([CH3:20])[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])=[O:10]

Participants

6

Reactant 4

HCID 14798Sodium HydroxideHCID 31373TetrachloroethyleneHCID 37079N-MethylhexylamineHCID 67165Nonanedioyl dichloride

Product 1

HCID 21542730HCID 21542730, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

10.5 grams of azeloylchloride were placed in a container holding 140 milliliters of tetrachloroethylene and dissolved. To the resulting mixture were added 9.2 grams of N-methyl-N-hexylamine, and 1.6 grams of NaOH dissolved in 200 milliliters of water. The completed mixture was agitated for 10-15 minutes; afterwards the organic layer was separated, washed with a dilute aqueous HCl solution. Following this the organic layer was washed with a 10% aqueous Na2CO3 solution and then washed with water. The washed organic layer was dried by contacting with MgSO4 and then the tetrachloroethylene was removed by application of a vacuum.

Workup

  1. dissolutiondissolved
  2. customafterwards the organic layer was separated
  3. washwashed with a dilute aqueous HCl solution
  4. washwas washed with a 10% aqueous Na2CO3 solution
  5. washwashed with water
  6. customThe washed organic layer was dried
  7. customthe tetrachloroethylene was removed by application of a vacuum

Sources & evidence

ORD record
ord-7ad7f1cd93754f1798ca634c3bde4ba4
Source dataset
uspto-grants-1976_04
Patent number
US03953346

Reaction notes

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