HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → HCID 21544463, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | 3-[(2-Oxo-2-phenylethyl)thio]-5-(trifluoromethyl)benzoic acid | HCID 21544480 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 21544463 | HCID 21544463 | — |
Reaction Steps
A solution of 2.6 g. (7.5 m moles) of 3-phenacylthio-5-trifluoromethylbenzoic acid and .75 ml. of 30% hydrogen peroxide in 15 ml. of acetic acid is heated on a steam bath for 1 hour, after which the reaction mixture is cooled and diluted with water to the turbidity point. The crystalline product which forms on standing is filtered, 1.0 g., m.p. 148°-151° C., and finally recrystallized from acetone-isopropyl ether, 850 mg., m.p. 154°-155° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03953595 |
| Source dataset | uspto-grants-1976_04 |
| ORD ID | ord-b757dd89d7a94a7da2931c597d24a457 |
| Source note | uspto-grants-1976_04 |