Diglycolamine → HCID 53842873, compound

HRID 1606855Notes

Reaction equation

HRID 1606855 reaction equation
[CH3:1][NH:2][C:3]1[CH:8]=[C:7](F)[CH:6]=[C:5]([NH:10][CH3:11])[C:4]=1[N+:12]([O-:14])=[O:13].[NH2:15][CH2:16][CH2:17][O:18][CH2:19][CH2:20][OH:21]>>[CH3:1][NH:2][C:3]1[CH:8]=[C:7]([NH:15][CH2:16][CH2:17][O:18][CH2:19][CH2:20][OH:21])[CH:6]=[C:5]([NH:10][CH3:11])[C:4]=1[N+:12]([O-:14])=[O:13]

Participants

3

Reactant 2

HCID 13578DiglycolamineHCID 54495836HCID 54495836, compound

Product 1

HCID 53842873HCID 53842873, compound

Procedure

0.01 mole (2 g) of 2-methylamino-6-methylamino-4-fluoronitrobenzene in 8 ml of 2-(2-aminoethoxy)ethanol was heated to 100° C. After 30 minutes the reaction medium was diluted with 20 ml of ice water and the desired product precipitated out. After filtering and vacuum drying in the presence of P2O5, it was recrystallized from isopropanol and then from ethyl acetate. The product melted at 132° C.

Workup

  1. customthe desired product precipitated out
  2. filtrationAfter filtering
  3. dry with materialvacuum drying in the presence of P2O5, it
  4. customwas recrystallized from isopropanol

Sources & evidence

ORD record
ord-54f38b446d264d33844c2b75432e8f83
Source dataset
uspto-grants-1989_09
Patent number
US04863482

Reaction notes

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