Acetic Acid → HCID 19850512, compound

HRID 1607477Notes

Reaction equation

HRID 1607477 reaction equation
O.C(O)(=O)C.[CH3:6][O:7][C:8]1[C:20]([N+]([O-])=O)=[CH:19][C:11]2[O:12][C:13]([CH3:18])([CH2:15][CH2:16][CH3:17])[O:14][C:10]=2[CH:9]=1>C(O)C>[CH3:6][O:7][C:8]1[CH:20]=[CH:19][C:11]2[O:12][C:13]([CH3:18])([CH2:15][CH2:16][CH3:17])[O:14][C:10]=2[CH:9]=1

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 962WaterHCID 19850511HCID 19850511, compound

Product 1

HCID 19850512HCID 19850512, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A suspension of 50 g of hydrogen-reduced iron powder in 150 ml of ethanol, to which 7 ml of water and 5 ml of acetic acid have been added, is heated under reflux. 0.08 mole (20.3 g) of 5-methoxy-6-nitro-2-methyl-2-propyl-1,3-benzodioxole is added portionwise. Heating is continued for 30 minutes after the end of the addition. The reaction mixture is filtered while boiling. 25 ml of a 7N solution of hydrochloric acid is added to the filtrate.

Workup

  1. temperatureis heated
  2. temperatureunder reflux
  3. temperatureHeating
  4. additionafter the end of the addition
  5. filtrationThe reaction mixture is filtered
  6. addition25 ml of a 7N solution of hydrochloric acid is added to the filtrate

Sources & evidence

ORD record
ord-37c0e9c54d4e49ec929931bb04a01d62
Source dataset
uspto-grants-1989_09
Patent number
US04865617

Reaction notes

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