Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | 1,2,4-Trichloro-3,5-dinitrobenzene | HCID 17584 | — |
| Reactant | Sodium ethoxide | HCID 2723922 | — |
| Product | HCID 19751981 | HCID 19751981 | — |
Reaction Steps
0.1 mole (27.15 g) of 3,5-dinitro-1,2,4-trichlorobenzene was heated to 75° C. in 110 ml of absolute ethanol. 0.2 mole of a 15% solution of sodium ethylate was added in absolute ethanol. Upon completion of the addition, the reaction mixture was heated for 30 minutes at 75° C. and then diluted with 300 g of an ice/water mixture. The expected product precipitated. After drying under vacuum and recrystallization from isopropyl ether, it melted at 78° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04865618 |
|---|
| Source dataset | uspto-grants-1989_09 |
|---|
| ORD ID | ord-daf4519eaffb48a3bb618bff805f6a69 |
|---|
| Source note | uspto-grants-1989_09 |
|---|
