Ethanol → HCID 19751981, compound

HRID 1607484Notes

Reaction equation

HRID 1607484 reaction equation
[N+:1]([C:4]1[C:5](Cl)=[C:6]([Cl:14])[CH:7]=[C:8]([N+:11]([O-:13])=[O:12])[C:9]=1Cl)([O-:3])=[O:2].[CH3:16][CH2:17][O-:18].[Na+].[CH2:20]([OH:22])[CH3:21]>>[N+:1]([C:4]1[C:5]([O:22][CH2:20][CH3:21])=[C:6]([Cl:14])[CH:7]=[C:8]([N+:11]([O-:13])=[O:12])[C:9]=1[O:18][CH2:17][CH3:16])([O-:3])=[O:2]

Participants

4

Reactant 3

HCID 702Ethanol2×HCID 175841,2,4-Trichloro-3,5-dinitrobenzeneHCID 2723922Sodium ethoxide

Product 1

HCID 19751981HCID 19751981, compound

Conditions

Temperature
75 °C

Procedure

0.1 mole (27.15 g) of 3,5-dinitro-1,2,4-trichlorobenzene was heated to 75° C. in 110 ml of absolute ethanol. 0.2 mole of a 15% solution of sodium ethylate was added in absolute ethanol. Upon completion of the addition, the reaction mixture was heated for 30 minutes at 75° C. and then diluted with 300 g of an ice/water mixture. The expected product precipitated. After drying under vacuum and recrystallization from isopropyl ether, it melted at 78° C.

Workup

  1. additionUpon completion of the addition
  2. customThe expected product precipitated
  3. dry with materialAfter drying under vacuum and recrystallization from isopropyl ether, it melted at 78° C.

Sources & evidence

ORD record
ord-daf4519eaffb48a3bb618bff805f6a69
Source dataset
uspto-grants-1989_09
Patent number
US04865618

Reaction notes

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