Azidotrimethylsilane → HCID 178420773, compound

HRID 1607585Notes

Reaction equation

HRID 1607585 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[C:3]([C:7]#[CH:8])[CH:2]=1.C[Si]([N:13]=[N+:14]=[N-:15])(C)C>O>[N:1]1[CH:6]=[CH:5][CH:4]=[C:3]([C:7]2[N:13]=[N:14][NH:15][CH:8]=2)[CH:2]=1

Participants

4

Reactant 2

HCID 78378AzidotrimethylsilaneHCID 1860033-Ethynylpyridine

Product 1

HCID 178420773HCID 178420773, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
150 °C

Procedure

In a glass-coated bomb tube 6.5 g (0.063 mol) of 3-pyridyl acetylene (T. Sakamoto et al., Synthesis (1983) 312) and 8.7 g (0.075 mol) of trimethylsilyl azide were mixed and heated to 150° C. for 20 h. After cooling the mixture was poured into water. A colorless solid, 68, formed, which was isolated by filtration and dried. Yield: 4.0 g (0.028 mol, 44%).

Workup

  1. temperatureAfter cooling the mixture
  2. customA colorless solid, 68, formed
  3. customwhich was isolated by filtration
  4. customdried

Sources & evidence

ORD record
ord-9debf404d4f24287a69b62a685367ca0
Source dataset
uspto-grants-1989_09
Patent number
US04866077

Reaction notes

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