1-Dodecanethiol → HCID 21613593, compound

HRID 1607859Notes

Reaction equation

HRID 1607859 reaction equation
[CH2:1](S)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[S:14](Cl)(Cl)(=O)=O.[CH2:19]([S:35]([OH:37])=[O:36])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]>>[CH2:12]([O:36][S:35]([CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])(=[O:37])=[S:14])[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

4

Reactant 3

HCID 81951-DodecanethiolHCID 24648Sulfuryl chlorideHCID 6914363HCID 6914363, compound

Product 1

HCID 21613593HCID 21613593, compound

Procedure

36 g of dodecane thiol are converted into the corresponding sulphenic acid chloride by reaction with sulphuryl chloride as described above. This compound is added to a suspension of 56 g of the compound obtainable under (a). The mixture is then stirred for 2 hours and concentrated by evaporation and the residue is recrystallized from ethanol. m.p. 56° to 57° C.

Workup

  1. concentrationconcentrated by evaporation
  2. customthe residue is recrystallized from ethanol

Sources & evidence

ORD record
ord-3f3c42455a78480e8e0bf93d72f81a96
Source dataset
uspto-grants-1989_09
Patent number
US04868099

Reaction notes

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