Tributylstannane → HCID 67876694, compound

HRID 1608367Notes

Reaction equation

HRID 1608367 reaction equation
[C:1]([C:3]1[CH:11]=[CH:10][C:6]([C:7]([OH:9])=[O:8])=[CH:5][CH:4]=1)#[CH:2].[CH2:12]([SnH:16]([CH2:21][CH2:22][CH2:23][CH3:24])[CH2:17][CH2:18][CH2:19][CH3:20])[CH2:13][CH2:14][CH3:15]>>[CH2:21]([Sn:16]([CH2:12][CH2:13][CH2:14][CH3:15])([CH2:17][CH2:18][CH2:19][CH3:20])[CH:2]=[CH:1][C:3]1[CH:11]=[CH:10][C:6]([C:7]([O:9][Sn:16]([CH2:17][CH2:18][CH2:19][CH3:20])([CH2:21][CH2:22][CH2:23][CH3:24])[CH2:12][CH2:13][CH2:14][CH3:15])=[O:8])=[CH:5][CH:4]=1)[CH2:22][CH2:23][CH3:24]

Participants

3

Reactant 2

HCID 5948TributylstannaneHCID 5897064-Ethynylbenzoic acid

Product 1

HCID 67876694HCID 67876694, compound

Conditions

Temperature
60 °C

Procedure

A mixture of 4-ethynylbenzoic acid (1.0 equiv.) and tri-n-butyltinhydride (1.0 equiv.) (Aldrich) is warmed to 60° C. for six hours. Kugelrohr distillation of the crude product gives tri-n-butylstannyl 4-[2'-(tri-n-butylstannyl)ethenyl]benzoate.

Workup

  1. distillationKugelrohr distillation of the crude product

Sources & evidence

ORD record
ord-10d41fb667134354a450206db2c4d117
Source dataset
uspto-grants-1989_09
Patent number
US04870188

Reaction notes

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