3,3-Dinitroazetidine → 3,3-Dinitroazetidinium 2,4-dinitroimidazolate

HRID 1608676Notes

Reaction equation

HRID 1608676 reaction equation
[N+:1]([C:4]1([N+:8]([O-:10])=[O:9])[CH2:7][NH:6][CH2:5]1)([O-:3])=[O:2].[N+:11]([C:14]1[NH:15][CH:16]=[C:17]([N+:19]([O-:21])=[O:20])[N:18]=1)([O-:13])=[O:12]>C(#N)C>[N+:11]([C:14]1[N-:15][CH:16]=[C:17]([N+:19]([O-:21])=[O:20])[N:18]=1)([O-:13])=[O:12].[N+:1]([C:4]1([N+:8]([O-:10])=[O:9])[CH2:7][NH2+:6][CH2:5]1)([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 52317063,3-DinitroazetidineHCID 178526857HCID 178526857, compound

Product 1

HCID 1317189183,3-Dinitroazetidinium 2,4-dinitroimidazolateYield 95%

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

3,3-Dinitroazetidine free base (1.0 g) was added to a solution of 2,4-dinitroimidazole (1.07 g) in 50 ml of warm acetonitrile. The solution was allowed to cool and the majority of the solvent evaporated. The remaining slurry was filtered and dried to give 1.98 g of the resultant product, 3,3-dinitroazetidinium 2,4-dinitroimidazolate (95% yield).

Workup

  1. temperatureto cool
  2. customthe majority of the solvent evaporated
  3. filtrationThe remaining slurry was filtered
  4. customdried

Sources & evidence

ORD record
ord-f2cc1d08b8f14befacdfcb47b96c50ce
Source dataset
uspto-grants-1995_03
Patent number
US05395945

Reaction notes

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