AC1LBHMA → HCID 20082685, compound

HRID 1608890Notes

Reaction equation

HRID 1608890 reaction equation
[CH2:1]([C:5]1[CH:10]=[CH:9][C:8]([Cl:11])=[CH:7][CH:6]=1)[CH2:2][CH:3]=[CH2:4].[CH3:12][SiH:13]([CH2:15][Si:16]([CH3:19])([CH3:18])[CH3:17])[CH3:14]>>[Cl:11][C:8]1[CH:7]=[CH:6][C:5]([CH2:1][CH2:2][CH2:3][CH2:4][Si:13]([CH3:14])([CH3:12])[CH2:15][Si:16]([CH3:19])([CH3:18])[CH3:17])=[CH:10][CH:9]=1

Participants

3

Reactant 2

HCID 582874AC1LBHMAHCID 110520324-(4-Chlorophenyl)-1-butene

Product 1

HCID 20082685HCID 20082685, compoundYield 70.8%

Procedure

About 33.3 g (0.2 mol) of 4-(3-butenyl)-1-chlorobenzene prepared in accordance with Example 1 (b) were silylated with 2,4,4-trimethyl-2,4-disilapentane (compare Example 1 (d) with Pt as catalyst to give 1-chloro-4-(5,5,7,7-tetramethyl-5,7disilaoctyl)benzene. The boiling point was 115° C. under 0.05 hPa, and the yield was 70.8% of theory.

Sources & evidence

ORD record
ord-0aa7fe9bcf794aa19bb62a6832ad44df
Source dataset
uspto-grants-1995_03
Patent number
US05399290

Reaction notes

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