HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 54344046, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | 4-Methylpyridine | HCID 7963 | — |
| Reactant | HCID 20083430 | HCID 20083430 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 54344046 | HCID 54344046 | 49% |
Reaction Steps
A solution of 9.8 g (40 mmol) 4-(4-formylphenylmethoxy)-benzonitrile, 4 ml (40 mmol) 4-methylpyridine and 4 ml acetic acid anhydride is heated to 120° C. for 18 h. One mixes with water, extracts with dichloromethane, dries the extract, evaporates and triturates with ether. One isolates 6.1 g of title compound (49% of theory) of the m.p. 149°-150° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05399575 |
| Source dataset | uspto-grants-1995_03 |
| ORD ID | ord-c7594c88b94d44adad69165e84c51793 |
| Source note | uspto-grants-1995_03 |