HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromooctane → 2,7-Dibromo-9,9-di-n-octylfluorene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromooctane | HCID 8140 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 2,7-Dibromofluorene | HCID 140073 | — |
| Catalyst | Tetrabutylammonium Bromide | HCID 74236 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 2,7-Dibromo-9,9-di-n-octylfluorene | HCID 5215321 | — |
Reaction Steps
1.25 g (3.85 mmol) of tetrabutyl ammonium bromide (TBAB) was added to a solution of 25 g (77 mmol) of 2,7-dibromofluorene and 36 g (185 mmol) of n-octylbromide in 100 mL of toluene, and a solution of 31 g (770 mmol) of NaOH in 50 mL of water was added and refluxed for 2 days.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06984461B2 |
| Source dataset | uspto-grants-2006_01 |
| ORD ID | ord-050bbce432964e12a2db3400b1b0b10f |
| Source note | uspto-grants-2006_01 |