Lead diacetate → HCID 86599837, compound

HRID 1611073Notes

Reaction equation

C([O-])(=O)C.[Pb+2:5].C([O-])(=O)C.[CH3:10][O:11][CH2:12][C:13]([OH:15])=[O:14]>>[CH3:10][O:11][CH2:12][C:13]([O-:15])=[O:14].[Pb+2:5].[CH3:10][O:11][CH2:12][C:13]([O-:15])=[O:14]

Participants

Reactant 2

HCID 9317Lead diacetate

HCID 12251Methoxyacetic Acid

Product 1

HCID 86599837HCID 86599837, compound

Conditions

Temperature: 100 °C

Procedure

A 500 mL round bottom flask was charged with lead (II) acetate (Alfa 10719, 50.4 g, 0.133 mol) and methoxyacetic acid (209.8 g, 2.3 mol). The contents of the reactor were heated to 100° C. with an external oil bath and the volatile materials were distilled at 100 to 50 torr, head temperature to 65° C. The distillate was identified as a mixture of acetic acid and methoxyacetic acid. The pressure was further reduced and the excess methoxyacetic acid was removed. The title product was isolated as a colorless viscous liquid and diluted in water to give 87.6 grams of product (31% lead). Thermo-gravimetric analysis in air to 800° C. gave 32.5% lead oxide, calculated 32.8%. IR (thin film) 3441, 2943, 2834, 1731, 1585, 1428, 1202, 1114.

Workup

distillationthe volatile materials were distilled at 100 to 50 torr, head temperature to 65° C
additionThe distillate was identified as a mixture of acetic acid and methoxyacetic acid
customthe excess methoxyacetic acid was removed

Sources & evidence

ORD record: ord-3ad780c1c35a4b35bbd93831279df6a9
Source dataset: uspto-grants-2006_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06984745B2

Reaction notes

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