Methyl Methacrylate → Benzene, ethenyl-, polymer with 1,3-butadiene

HRID 1611564Notes

Reaction equation

[CH2:1]=[CH:2][CH:3]=[CH2:4].[CH2:5]=[CH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.C(#N)C=C.C(OC)(=O)C(C)=C>>[CH2:1]=[CH:2][CH:3]=[CH2:4].[CH2:5]=[CH:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1

Participants

Reactant 4

HCID 6658Methyl Methacrylate

HCID 7501Styrene

HCID 78451,3-Butadiene

HCID 7855Acrylonitrile

Product 1

HCID 62697Benzene, ethenyl-, polymer with 1,3-butadiene

Procedure

The refractive indices of butadiene, styrene, acrylonitrile and methyl methacrylate homo-polymers are 1.515, 1.591, 1.515 and 1.491 respectively. A butadiene/styrene ratio of 85:15 gives a calculated refractive index of (0.85×1.515)+(0.15×1.591)=˜1.526.

Sources & evidence

ORD record: ord-8a8f4a4687564034b96d71623eb5ec90
Source dataset: uspto-grants-2006_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06989190B2

Reaction notes

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