Azobisisobutyronitrile → HCID 22256030, compound

HRID 1611746Notes

Reaction equation

HRID 1611746 reaction equation
[CH3:1][C:2]1[CH:14]=[CH:13][CH:12]=[C:11]([CH3:15])[C:3]=1[C:4]([O:6][CH2:7][CH2:8][O:9][CH3:10])=[O:5].S(Cl)([Cl:19])(=O)=O.CC(N=NC(C#N)(C)C)(C#N)C>O>[Cl:19][CH2:1][C:2]1[CH:14]=[CH:13][CH:12]=[C:11]([CH3:15])[C:3]=1[C:4]([O:6][CH2:7][CH2:8][O:9][CH3:10])=[O:5]

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 24648Sulfuryl chlorideHCID 22256034HCID 22256034, compound

Product 1

HCID 22256030HCID 22256030, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

10.4 g of 2-methoxyethyl 2,6-dimethylbenzoate are admixed at room temperature with 5.4 g of sulfuryl chloride and 40 mg of AIBN. The mixture is stirred at 60–90° C. for 1–2 h. Afterwards, the mixture is admixed with 20 ml of water, the phases are separated and the organic phase is dried over magnesium sulfate. The product is distilled under high vacuum (0.02 mbar, 95–103° C.). Yield: 6.4 g (66% of theory; 91.8 area %).

Workup

  1. customthe phases are separated
  2. dry with materialthe organic phase is dried over magnesium sulfate
  3. distillationThe product is distilled under high vacuum (0.02 mbar, 95–103° C.)

Sources & evidence

ORD record
ord-1dc20f0b813c4a5190c712805390aec3
Source dataset
uspto-grants-2006_01
Patent number
US06989462B2

Reaction notes

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