Formaldehyde → HCID 178440781, compound

Participants

Reaction Steps

3-Mercapto-1,2,4-triazole (20.2 g, 0.2 mol), 2,6-di-tertbutylphenol (41.2 g, 0.2 mol), paraformaldehyde (6.0 g, 0.2M) and di-n-butylamine (2 ml) are heated, under reflux, in ethanol (100 ml) for ten hours. The reaction mixture is cooled, and the product is crystallised as a white solid (43 g, 67% of theory) having a m.p. of 184°-185° C. (Found C=63.39; H=8.03; N=13.29; S=10.20 C17H25N3OS requires C=63.95; H=7.84; N=13.17 and S=10.03%).

Provenance & Evidence