Acrylonitrile → HCID 10420903, compound

HRID 1612671Notes

Reaction equation

HRID 1612671 reaction equation
[CH:1]([O:4][P:5]([C:7]([CH3:10])([CH3:9])[CH3:8])[OH:6])([CH3:3])[CH3:2].[Na].[C:12](#[N:15])[CH:13]=[CH2:14]>>[C:12]([CH2:13][CH2:14][P:5]([C:7]([CH3:10])([CH3:9])[CH3:8])(=[O:6])[O:4][CH:1]([CH3:3])[CH3:2])#[N:15]

Participants

4

Reactant 3

HCID 7855AcrylonitrileHCID 5360545SodiumHCID 19090901HCID 19090901, compound

Product 1

HCID 10420903HCID 10420903, compound

Procedure

To 15.7 g of t-butylphosphonous acid-isopropylester in 6.3 ml of acrylonitrile are added 21 ml of sodium isopropylate (0.25 molar). After the exothermic reaction (the temperature rises to 100°) the suspension is filtered, the filtrate evaporated and the residue distillated to yield isopropyl 2-cyanoethyl(t-butyl)phosphinate as an oil, b.p. 121°/8 Pa, nD20 =1.4480.

Workup

  1. customAfter the exothermic reaction (the temperature
  2. customrises to 100°
  3. filtrationis filtered
  4. customthe filtrate evaporated

Sources & evidence

ORD record
ord-16b9999b4bf44ab0b5ef6db1361eca56
Source dataset
uspto-grants-1993_03
Patent number
US05190933

Reaction notes

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