Hexachloroethane → HCID 14949191, compound

Participants

Reaction Steps

The reactants used in the foregoing general procedure were hexachloroethane (0.0902 mol, 21.79 g), triphenylphosphine (0.0911 mol, 24.14 g), triethylamine (0.0902 mol, 12.8 mL), N-trimethylsilyl sulfonamide (3e) (0.0902 mol, 20.66 g). The identity of the reaction product was confirmed by the presence of signals at the following shifts in the 1H NMR spectrum: 90 MHz (CHCl3) 0.05 (s, 9H), 2.12 (m, 2H, SCH2CH2), 3.38 (t, 2H, SCH2), 3.45 (t, 2H, ClCH2).

Provenance & Evidence