Hexachloroethane → HCID 14949191, compound

HRID 1613847Notes

Reaction equation

[Cl:1]C(Cl)(Cl)C(Cl)(Cl)Cl.C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.C(N(CC)CC)C.[CH3:35][Si:36]([CH3:46])([CH3:45])[NH:37][S:38]([CH2:41][CH2:42][CH2:43][Cl:44])(=O)=[O:39]>>[CH3:35][Si:36]([CH3:46])([CH3:45])[N:37]=[S:38]([Cl:1])([CH2:41][CH2:42][CH2:43][Cl:44])=[O:39]

Participants

Reactant 4

HCID 6214Hexachloroethane

HCID 8471Triethylamine

HCID 11776Triphenylphosphine

HCID 14949187HCID 14949187, compound

Product 1

HCID 14949191HCID 14949191, compound

Procedure

The reactants used in the foregoing general procedure were hexachloroethane (0.0902 mol, 21.79 g), triphenylphosphine (0.0911 mol, 24.14 g), triethylamine (0.0902 mol, 12.8 mL), N-trimethylsilyl sulfonamide (3e) (0.0902 mol, 20.66 g). The identity of the reaction product was confirmed by the presence of signals at the following shifts in the 1H NMR spectrum: 90 MHz (CHCl3) 0.05 (s, 9H), 2.12 (m, 2H, SCH2CH2), 3.38 (t, 2H, SCH2), 3.45 (t, 2H, ClCH2).

Sources & evidence

ORD record: ord-39994cf9bf1e4866a15293a0da9acc51
Source dataset: uspto-grants-1993_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05194557

Reaction notes

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