Water → HCID 86746627, compound

HRID 1613929Notes

Reaction equation

HRID 1613929 reaction equation
C(=O)([O-])[O-].[K+].[K+].O.[CH:8](/[C:17]1[C:26]([CH3:27])=[C:25]([O:28]C(=O)C)[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[N:18]=1)=[CH:9]/[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>CO>[CH:8](/[C:17]1[CH:26]([CH3:27])[C:25](=[O:28])[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[N:18]=1)=[CH:9]/[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

5

Reactant 3

HCID 962Water2×HCID 11430Potassium CarbonateHCID 15007051HCID 15007051, compound

Product 1

HCID 86746627HCID 86746627, compoundYield 86%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

205 mg (1.49 mmols) of potassium carbonate and 2 ml of water were added to a solution of 483 mg (1.49 mmols) of 2-(cis-1-nonenyl)-3-methyl-4-acetoxyquinoline, 1 ml of water and 30 ml of methanol and stirred at room temperature for 13 hours. Thereafter, the solution was treated and purified in the same manner as in Example 2 to obtain 360 mg (yield 86%) of 2-(cis-1-nonenyl)-3-mehtyl-4-quinolone.

Workup

  1. additionThereafter, the solution was treated
  2. custompurified in the same manner as in Example 2

Sources & evidence

ORD record
ord-7254b9ab265246f986880b0319da2980
Source dataset
uspto-grants-1993_03
Patent number
US05194617

Reaction notes

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