HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pyrogallol → 3-(Benzyloxy)benzene-1,2-diol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pyrogallol | HCID 1057 | — |
| Reactant | Benzyl Bromide | HCID 7498 | — |
| Reactant | Triethyl borate | HCID 9009 | — |
| Solvent | Cyclohexane ethylacetate | HCID 21867204 | — |
| Product | 3-(Benzyloxy)benzene-1,2-diol | HCID 11977435 | — |
Reaction Steps
Using the procedure of Example 13, 25.22 g of pyrogallol, 35.1 ml of triethyl borate and 23.76 ml of benzyl bromide were reacted to obtain 33.8 g of the expected product in the form of a thick red oil after chromatography on silica eluting with a cyclohexane - ethyl acetate (6-4) mixture (Yield: 78%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05198571 |
| Source dataset | uspto-grants-1993_03 |
| ORD ID | ord-afab7cd2eb86424fa011bb25e42cdd54 |
| Source note | uspto-grants-1993_03 |