Butyl ether → HCID 131731642, compound

HRID 1614838Notes

Reaction equation

HRID 1614838 reaction equation
[CH:1](=[C:3]1[CH2:8][CH:7]2[CH2:9][CH:4]1[CH:5]=[CH:6]2)[CH3:2].[CH2:10](OCCCC)CCC.[Cl-].C([Al+]CC)C>C1C2C3C=CC(C2C=C1)C3>[CH2:1]1[CH:3]2[CH:4]3[CH:5]=[CH:6][CH:7]([CH:8]2[CH:10]=[CH:2]1)[CH2:9]3.[CH:1](=[C:3]1[CH2:8][CH:7]2[CH2:9][CH:4]1[CH:5]=[CH:6]2)[CH3:2]

Participants

5

Reactant 3

HCID 8909Butyl etherHCID 27756EthylidenenorborneneHCID 16686102Diethyl aluminum chloride

Product 1

HCID 131731642HCID 131731642, compound

Reagents, catalysts & solvents 1

HCID 6492DicyclopentadieneSolvent

Procedure

Irganox™ 1010 (0.24 g, Ciba Specialty Chemical Corp, Tarrytown, N.Y.) and Irgafos™ 168 (0.72 g, Ciba) were placed in an oven-dried 125 mL Erlenmeyer flask which was then capped with a septum and purged with nitrogen. Ethylidenenorbornene (35.6 mL, 0.26 mol) was added and the mixture was stirred for several minutes to dissolve the solids. Butyl ether (2.4 mL) and 9.1 mL of a 10 vol % solution of diethylaluminumchloride in dicyclopentadiene were then added. This solution is denoted Mixture 4B.

Workup

  1. customwas then capped with a septum
  2. custompurged with nitrogen
  3. dissolutionto dissolve the solids

Sources & evidence

ORD record
ord-0ee3dfd8d10d4620840143a1481b15f9
Source dataset
uspto-grants-2014_07
Patent number
US08763231B2

Reaction notes

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