Toluene → HCID 131731648, compound

HRID 1616949Notes

Reaction equation

HRID 1616949 reaction equation
Cl[P:2]1(Cl)[N:7]=[P:6](Cl)(Cl)[N:5]=[P:4](Cl)(Cl)[N:3]=1.[C:13]1([CH3:19])[CH:18]=CC=C[CH:14]=1>>[CH2:14]([P:2]1([CH2:19][C:13](=[CH2:14])[CH3:18])[N:7]=[P:6]([CH2:14][C:13](=[CH2:19])[CH3:18])([CH2:14][C:13](=[CH2:19])[CH3:18])[N:5]=[P:4]([CH2:18][C:13](=[CH2:14])[CH3:19])([CH2:14][C:13](=[CH2:19])[CH3:18])[N:3]=1)[C:13](=[CH2:19])[CH3:18]

Participants

3

Reactant 2

HCID 1140TolueneHCID 220225Hexachlorocyclotriphosphazene2×

Product 1

HCID 131731648HCID 131731648, compound

Conditions

Temperature
25 °C

Procedure

Furthermore, into the 5-liter flask as described above is put a solution of hexachlorocyclotriphosphazene in toluene (700 g (6.0 unit mol) of hexachlorocyclotriphosphazene, 3,500 mL of toluene). The slurry solution of 2-methyl-2-proper-1-ol sodium salt is added dropwise thereto at 5° C. or lower over 6 hours, followed by warming to 25° C. and stirring for 4 hours, to obtain a solution of hexamethallylcyclotriphosphazene.

Workup

  1. additionThe slurry solution of 2-methyl-2-proper-1-ol sodium salt is added dropwise

Sources & evidence

ORD record
ord-4ebaa8c3e1a84a47b8ae82294f37f2c9
Source dataset
uspto-grants-2014_07
Patent number
US08765878B2

Reaction notes

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