Benzoyl Peroxide → HCID 67466145, compound

HRID 1619920Notes

Reaction equation

HRID 1619920 reaction equation
[Br:1][C:2]1[CH:17]=[CH:16][C:5]2[N:6]=[C:7]([C:9]3[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][CH:10]=3)[O:8][C:4]=2[CH:3]=1.[Br:18]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Br:1][C:2]1[CH:17]=[CH:16][C:5]2[N:6]=[C:7]([C:9]3[CH:10]=[CH:11][C:12]([CH2:15][Br:18])=[CH:13][CH:14]=3)[O:8][C:4]=2[CH:3]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 67462314HCID 67462314, compound

Product 1

HCID 67466145HCID 67466145, compound

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

3.00 g (10.41 mmol) 6-bromo-2-p-tolyl-benzoxazole are stirred together with 1.90 g (10.68 mmol) N-bromosuccinimide, 10.00 mg (0.04 mmol) dibenzoylperoxide and 60 ml carbon tetrachloride for 2 h at 90°. The reaction mixture is filtered through kieselguhr, then the solv. is eliminated by rotary evaporation in vacuo and the residue is recrystallised from petroleum ether.

Workup

  1. filtrationThe reaction mixture is filtered through kieselguhr
  2. customis eliminated by rotary evaporation in vacuo
  3. customthe residue is recrystallised from petroleum ether

Sources & evidence

ORD record
ord-1ddd917be4544b019c419b9feca430dc
Source dataset
uspto-grants-2014_07
Patent number
US08772323B2

Reaction notes

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