tert-Butyl acrylate → HCID 24859311, compound

HRID 1627942Notes

Reaction equation

HRID 1627942 reaction equation
[C:1]([Si:5]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH:17]=[CH2:18])([CH3:7])[CH3:6])([CH3:4])([CH3:3])[CH3:2].[C:19]([O:23][C:24]([CH3:27])([CH3:26])[CH3:25])(=[O:22])C=C>>[Si:5]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16]/[CH:17]=[CH:18]/[C:19]([O:23][C:24]([CH3:27])([CH3:26])[CH3:25])=[O:22])([C:1]([CH3:3])([CH3:4])[CH3:2])([CH3:6])[CH3:7]

Participants

3

Reactant 2

HCID 15458tert-Butyl acrylateHCID 10869380HCID 10869380, compound

Product 1

HCID 24859311HCID 24859311, compoundYield 95%

Procedure

The representative procedure was followed using tert-butyl(dec-9-enyloxy)dimethylsilane (135 mg, 0.50 mmol), tert-butyl acrylate (128 mg, 1.00 mmol) and Grubbs-2 catalyst (8.5 mg, 0.01 mmol). Column chromatography on silica gel (eluting with 2% EtOAc/hexanes) afforded the product as a colorless oil (176 mg, 95%).

Sources & evidence

ORD record
ord-20931112c79c426393e4d2936545be6f
Source dataset
uspto-grants-2014_07
Patent number
US08785665B2

Reaction notes

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