tert-Butyl acrylate → HCID 58288927, compound

HRID 1627945Notes

Reaction equation

HRID 1627945 reaction equation
[C:1]([Si:5]([O:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[CH2:15][CH:16]=[CH2:17])([CH3:7])[CH3:6])([CH3:4])([CH3:3])[CH3:2].[C:18]([O:22][C:23]([CH3:26])([CH3:25])[CH3:24])(=[O:21])C=C>>[Si:5]([O:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][C:10]=1[CH2:15]/[CH:16]=[CH:17]/[C:18]([O:22][C:23]([CH3:26])([CH3:25])[CH3:24])=[O:21])([C:1]([CH3:4])([CH3:3])[CH3:2])([CH3:7])[CH3:6]

Participants

3

Reactant 2

HCID 15458tert-Butyl acrylateHCID 11482047HCID 11482047, compound

Product 1

HCID 58288927HCID 58288927, compoundYield 91%

Procedure

The representative procedure was followed using tert-butyl(2-allylphenoxy)dimethylsilane (124 mg, 0.50 mmol), tert-butyl acrylate (128 mg, 1.00 mmol) and Grubbs-2 catalyst (8.5 mg, 0.01 mmol). Column chromatography on silica gel (eluting with 3% EtOAc/hexanes) afforded the product as a colorless oil (158 mg, 91%).

Sources & evidence

ORD record
ord-bdfea253a2204b57808af527dfdca1a6
Source dataset
uspto-grants-2014_07
Patent number
US08785665B2

Reaction notes

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