HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azide → HCID 57517329, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azide | HCID 33558 | — |
| Reactant | 4-(1-Azido-1-methyl-ethyl)-1-chloro-2-methyl-benzene | HCID 57517328 | — |
| Catalyst | Platinum dioxide monohydrate | HCID 11139377 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 57517329 | HCID 57517329 | — |
Reaction Steps
A solution of azide INT 21 (4.58 g, 21.84 mmol) in MeOH (100 mL) was hydrogenated at room temperature under atmospheric pressure for 6 hours in the presence of platinum dioxide hydrate (268 mg, 1.1 mmol). The mixture was filtered through Celite and concentrated. The crude was used without further purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08791100B2 |
| Source dataset | uspto-grants-2014_07 |
| ORD ID | ord-50ccf86980934dd5ace9df5ff3dd3c1c |
| Source note | uspto-grants-2014_07 |