Cyclohexanone Oxime → HCID 57954499, compound

HRID 1630438Notes

Reaction equation

HRID 1630438 reaction equation
[C:1]1(=[N:7][OH:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.C([O-])(=O)C.[Pb+4].[C:26]([CH2:28][C:29]([OH:31])=[O:30])#[N:27]>>[C:26]([CH2:28][C:29]([O:31][C:1]1([N:7]=[O:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1)=[O:30])#[N:27]

Participants

4

Reactant 3

HCID 7517Cyclohexanone OximeHCID 9740Cyanoacetic acidHCID 178418268HCID 178418268, compound

Product 1

HCID 57954499HCID 57954499, compound

Procedure

1-Nitrosocyclohexyl 2-cyanoacetate was prepared from cyclohexanone oxime, lead tetraacetate and cyanoacetic acid using conditions of General Method 3. 1H NMR (250 MHz, chloroform-d) δ 3.62 (2H, s), 2.01-2.21 (2H, m), 1.70-1.97 (5H, m), 1.41-1.69 (3H, m).

Sources & evidence

ORD record
ord-5564068ea29d43f19758a69089a727a3
Source dataset
uspto-grants-2014_07
Patent number
US08791134B2

Reaction notes

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