Chloroform → 1,1,1-Trichlorononane
Reaktionsgleichung
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[CH:27]([Cl:30])([Cl:29])[Cl:28]>>[Cl:28][C:27]([Cl:30])([Cl:29])[CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]Komponenten
4
Versuchsvorschrift
It has been disclosed that, when chloroform is reacted with oct-1-ene in the presence of benzoyl peroxide, 1,1,1-trichlorononane is formed in a yield of from 22 to 40%, based on the olefin, and with a selectivity of from 41 to 48%, conversion of the olefin being incomplete (J. Amer. Chem. Soc. 69 (1947), 1100-1104, in particular page 1104; and J. Chem. Soc. 1963, 3921-3927, in particular page 3927). The free-radical addition reactions of chloroform with other olefins also in general give only moderate yields (C. Walling and E. S. Hugser, Org. Reactions 13 (1963), 129).
Quellen und Nachweise
- ORD-Eintrag
- ord-6e2966d86d8a4e0fa25a0e28e7ba524e
- Quelldatensatz
- uspto-grants-1984_10
- Patentnummer
- US04475003
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