Ethyl Acrylate → Ethyl 3-(perfluorohexyl)propanoate

HRID 1632928Notes

Reaction equation

HRID 1632928 reaction equation
[C:1](I)([C:4]([C:7]([C:10]([C:13]([C:16]([F:19])([F:18])[F:17])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2].[C:21]([O:25][CH2:26][CH3:27])(=[O:24])[CH:22]=[CH2:23]>>[C:1]([CH2:23][CH2:22][C:21]([O:25][CH2:26][CH3:27])=[O:24])([C:4]([C:7]([C:10]([C:13]([C:16]([F:19])([F:18])[F:17])([F:15])[F:14])([F:12])[F:11])([F:9])[F:8])([F:6])[F:5])([F:3])[F:2]

Participants

3

Reactant 2

HCID 8821Ethyl AcrylateHCID 677331,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane

Product 1

HCID 11761588Ethyl 3-(perfluorohexyl)propanoate

Procedure

By causing 23 g. of C6F13I and 5 g. of ethyl acrylate to react under the conditions of Examples 3 to 7, there was obtained C6F13C2H4COOC2H5 and a dimer of the formula: ##STR6##

Sources & evidence

ORD record
ord-b6b8ca7246f9474caecce4419e030006
Source dataset
uspto-grants-1984_10
Patent number
US04478760

Reaction notes

Loading…