Ethanol → HCID 20440090, compound

HRID 1633213Notes

Reaction equation

HRID 1633213 reaction equation
[NH2:1][NH2:2].[N+:3]([O-:6])([OH:5])=[O:4].[N:7]#[C:8][NH2:9].C(O)C>>[N+:3]([O-:6])([O-:5])=[O:4].[NH2:1][N+:2]([NH2:3])=[C:8]([NH2:9])[NH2:7]

Participants

5

Reactant 4

HCID 702EthanolHCID 944Nitric AcidHCID 9321HydrazineHCID 9864Cyanamide

Product 1

HCID 20440090HCID 20440090, compound

Conditions

Temperature
20 °C

Procedure

64% Hydrazine solution (50 g, 1 mole) and 70% nitric acid (45 g, 0.5 mole) were carefully mixed in 200 ml of ethanol. 50% Aqueous cyanamide solution (42 g, 0.5 mole) was added and the mixture refluxed two hours. The solution was cooled to 20° C. precipitating the product which was then recrystallized from methanol giving 15 g of white solid.

Workup

  1. temperaturethe mixture refluxed two hours
  2. customprecipitating the product which
  3. customwas then recrystallized from methanol giving 15 g of white solid

Sources & evidence

ORD record
ord-fb135aa95d3441818523b457770b4e96
Source dataset
uspto-grants-1984_10
Patent number
US04479917

Reaction notes

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