Cyanuric chloride → HCID 20153015, compound

HRID 1633373Notes

Reaction equation

HRID 1633373 reaction equation
[CH:1]1([N:7]([CH2:54][CH2:55]N2CC(C)(C)NC(C)(C)C2=O)[C:8]2[N:13]=[C:12]([N:14]([CH:28]3C[CH2:32][CH2:31][CH2:30][CH2:29]3)CCN3CC(C)(C)NC(C)(C)C3=O)[N:11]=[C:10]([N:34]([CH:48]3[CH2:53][CH2:52]CC[CH2:49]3)[CH2:35][CH2:36][N:37]3[CH2:42][C:41]([CH3:44])([CH3:43])[NH:40][C:39]([CH3:46])([CH3:45])[C:38]3=[O:47])[N:9]=2)[CH2:6][CH2:5]CCC1.C1(NCCN2CC(C)(C)NC(C)(C)C2=O)CCCCC1.N1C(Cl)=NC(Cl)=NC=1Cl.[OH-].[Na+]>C1(C)C=CC=CC=1>[N:14]1([C:12]2[N:13]=[C:8]([N:7]3[CH2:1][CH2:6][CH2:5][CH2:55][CH2:54]3)[N:9]=[C:10]([N:34]([CH:48]([CH3:49])[CH2:53][CH3:52])[CH2:35][CH2:36][N:37]3[CH2:42][C:41]([CH3:43])([CH3:44])[NH:40][C:39]([CH3:46])([CH3:45])[C:38]3=[O:47])[N:11]=2)[CH2:32][CH2:31][CH2:30][CH2:29][CH2:28]1

Participants

6

Reactant 4

HCID 7954Cyanuric chlorideHCID 14798Sodium HydroxideHCID 15165099Piperazinone, 1-[2-(cyclohexylamino)ethyl]-3,3,5,5-tetramethyl-HCID 226228151,1',1''-{1,3,5-Triazine-2,4,6-triyltris[(cyclohexylazanediyl)ethane-2,1-diyl]}tris(3,3,5,5-tetramethylpiperazin-2-one)

Product 1

HCID 20153015HCID 20153015, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

In a manner analogous to that described hereinabove, a compound identified as 2,4,6-tris[cyclohexyl[2-(3,3,5,5-tetramethyl-2-oxo-1-piperazinyl)ethyl]amino]-1,3,5-triazine which has the following structure: ##STR27## is prepared by reacting 0.046 mole 1-[2-(cyclohexylamino)ethyl]-3,3,5,5-tetramethyl-2-piperazinone and 0.01 mole cyanuric chloride, 1.2 g sodium hyroxide and 150 ml toluene. The reaction was carried out at 200° C. for 10 hr. The resulting light straw colored solid isolated was recrystallized from acetone and analyzed. It had a m p of 179°-180° C. and was off-white in color.

Workup

  1. custom##STR27## is prepared
  2. customThe resulting light straw colored solid isolated
  3. customwas recrystallized from acetone
  4. customa m p of 179°-180° C.

Sources & evidence

ORD record
ord-a3bd93c4726f4ccdad0c38fc12032f5b
Source dataset
uspto-grants-1984_10
Patent number
US04480092

Reaction notes

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