Potassium Carbonate → HCID 59032958, compound

HRID 1634718Notes

Reaction equation

[OH:1][C:2]1[C:14]2[C:13](=[O:15])[C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[C:6]=2[CH:5]=[CH:4][CH:3]=1.S(C1C=CC([N+]([O-])=O)=CC=1)(O[CH2:20][C@H:21]1[O:23][CH2:22]1)(=O)=O.C(=O)([O-])[O-].[K+].[K+]>>[O:23]1[CH2:22][C@H:21]1[CH2:20][O:1][C:2]1[C:14]2[C:13](=[O:15])[C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[C:6]=2[CH:5]=[CH:4][CH:3]=1

Participants

Reactant 3

HCID 11430Potassium Carbonate

HCID 806631-Hydroxyfluoren-9-one

HCID 10868995(S)-(+)-Glycidyl-4-nitrobenzoate

Product 1

HCID 59032958HCID 59032958, compoundYield 20.3%

Procedure

Prepared from 1-hydroxy-9-fluorenone (3.0 g, 15.2 mmol), (S)-glycidyl nosylate (3.06 g, 15.2 mmol) and potassium carbonate (2.1 g, 15.2 mmol) according to the procedure used for Intermediate 1 to give 0.78 g product as a yellow solid.

Sources & evidence

ORD record: ord-a2ecfcb0dd1c4fc1a15344ac097e01ad
Source dataset: uspto-grants-2003_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06506901B2

Reaction notes

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