HuagongsheHuagongshe Chemistry Print Report · For research reference only
Glycidoxypropyltrimethoxysilane → 1-Methoxycarbonyl-2-vinvlcyclopropane-1-carboxylic acid-[2-hydroxy-3-(3-trimethoxysilylpropoxy)propyl]ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Glycidoxypropyltrimethoxysilane | HCID 17317 | — |
| Reactant | 2-Vinylcyclopropane-1,1-dicarboxylic acid monomethyl ester | HCID 10855915 | — |
| Reactant | Lithium perchlorate | HCID 23665649 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1-Methoxycarbonyl-2-vinvlcyclopropane-1-carboxylic acid-[2-hydroxy-3-(3-trimethoxysilylpropoxy)propyl]ester | HCID 53650266 | 83% |
Reaction Steps
A mixture of 10.0 g (58 mmol) 1-methoxycarbonyl-2-vinylcyclopropane carboxylic acid, 14.0 g trimethoxysilylpropylglycidyl-ether and 100 mg lithium perchlorate in 20 ml dichloromethane were stirred at room temperature for 15 days. After removal of solvent in vacuo, 20 g (83% yield) of a clear, yellow viscous liquid remained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06034151 |
| Source dataset | uspto-grants-2000_03 |
| ORD ID | ord-1f4adc3e9d2645b0ad6ccad56c1eab37 |
| Source note | uspto-grants-2000_03 |