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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1637067Generated: October 31, 2026

Oxygen → 1-Adamantanol

https://huagongshe.com/reaction/1637067

Reaction equation

Participants

RoleNameHCIDCharge
ReactantOxygenHCID 977—
ReactantFluoreneHCID 6853—
ReactantAdamantaneHCID 9238—
ReactantN-HydroxyphthalimideHCID 10665—
Product1-AdamantanolHCID 64152—
ProductFluoreneoneHCID 22281833—

Reaction Steps

In page 762 of the "Lecture Draft II" (1994) of 67th Spring Annual Meeting of Chemical Society of Japan, it is reported that oxidation of an alcohol such as benzyl alcohol or benzhydrol with air using vanadomolybdophosphoriate and N-hydroxyphthalimide provides a ketone such as acetophenone or benzophenone in a high yield, and that oxidation of fluorene or adamantane with oxygen using N-hydroxyphthalimide gives a corresponding adamantanol or fluorenone.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06037507
Source datasetuspto-grants-2000_03
ORD IDord-7ca3d62deb444295a7f83ee2af8410dc
Source noteuspto-grants-2000_03