HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → 1-Adamantanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Fluorene | HCID 6853 | — |
| Reactant | Adamantane | HCID 9238 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Product | 1-Adamantanol | HCID 64152 | — |
| Product | Fluoreneone | HCID 22281833 | — |
Reaction Steps
In page 762 of the "Lecture Draft II" (1994) of 67th Spring Annual Meeting of Chemical Society of Japan, it is reported that oxidation of an alcohol such as benzyl alcohol or benzhydrol with air using vanadomolybdophosphoriate and N-hydroxyphthalimide provides a ketone such as acetophenone or benzophenone in a high yield, and that oxidation of fluorene or adamantane with oxygen using N-hydroxyphthalimide gives a corresponding adamantanol or fluorenone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06037507 |
| Source dataset | uspto-grants-2000_03 |
| ORD ID | ord-7ca3d62deb444295a7f83ee2af8410dc |
| Source note | uspto-grants-2000_03 |