HRID1637388

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID82128

Carbonochloridic acid, 4-methoxyphenyl ester

C8H7ClO3

结构：CS(=O)(=O)N(CCCl)N(C(=O)Oc1ccccc1)S(C)(=O)=O

HCID9799547

未命名化合物

PRODUCTS

生成物

结构：COc1ccc(OC(=O)N(N(CCCl)S(C)(=O)=O)S(C)(=O)=O)cc1

HCID9930877

未命名化合物

PROCEDURE

实验过程

1,2-Bis(methylsulfonyl)-1-(2-chloroethyl)-2-[(4-methoxyphenoxy)carbonyl]hydrazine (compound 10g) was prepared by reacting compound 2 with 4-methoxyphenyl chloroformate using a procedure similar to the one employed for compound 10d. The product was recrystallized from ethanol, and the yield was about 30.0% by weight. The Mp of the product was approximately 119-121° C. 1H NMR (CDCl3): δ 7.1 and 6.9 (4H, 2d, aromatic H), 3.6-4.2 (4H, m, CH2CH2Cl), 3.8 (3H, s, OCH3), 3.5 and 3.2 (6H, 2s, 2 CH3SO2).

WORKUP

后处理

customThe product was recrystallized from ethanol
customwas approximately 119-121° C