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HRID1637389

反应详情

EQUATION

反应方程式

HRID 1637389 的结构方程式

REACTANTS

反应物

2
结构：O=C(Cl)OCc1ccc([N+](=O)[O-])cc1
HCID78205

Carbonochloridic acid, (4-nitrophenyl)methyl ester

C8H6ClNO4

结构：CS(=O)(=O)N(CCCl)N(C(=O)Oc1ccccc1)S(C)(=O)=O
HCID9799547

未命名化合物

PRODUCTS

生成物

1
结构：CS(=O)(=O)N(CCCl)N(C(=O)OCc1ccc([N+](=O)[O-])cc1)S(C)(=O)=O
HCID9932392

未命名化合物

PROCEDURE

实验过程

1,2-Bis(methylsulfonyl)-1-(2-chloroethyl)-2-[(4-nitrobenzyloxy)carbonyl]hydrazine (compound 10h) was prepared by reacting compound 2 with 4-nitrobenzyl chloroformate using a procedure similar to that employed for compound 10d. The product was recrystallized from ethanol, and the yield was approximately 22.9% by weight. The Mp was approximately 132-133° C. 1H NMR (acetone-d6): δ 8.3 and 7.8 (4H, 2d, aromatic H), 5.6 (2H, s, ArCH2), 3.6-4.2 (4H, m, CH2CH2Cl), 3.6 and 3.3 (6H, 2s, 2 CH3SO2).

WORKUP

后处理

  1. customThe product was recrystallized from ethanol