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HRID1637393

反应详情

EQUATION

反应方程式

HRID 1637393 的结构方程式

REACTANTS

反应物

2
结构：O=[N+]([O-])c1ccc(Cl)cc1CO
HCID556066

5-Chloro-2-nitrobenzyl alcohol

C7H6ClNO3

结构：CS(=O)(=O)N(CCCl)N(C(=O)OCc1ccccc1[N+](=O)[O-])S(C)(=O)=O
HCID19348412

未命名化合物

PRODUCTS

生成物

1
结构：CS(=O)(=O)N(CCCl)N(C(=O)OCc1cc(Cl)ccc1[N+](=O)[O-])S(C)(=O)=O
HCID19348411

未命名化合物

PROCEDURE

实验过程

1,2-Bis(methylsulfonyl)-1-(2-chloroethyl)-2-[(5-chloro-2-nitrobenzyloxy)carbonyl]hydrazine (compound 13c) was prepared from 5-chloro-2-nitrobenzyl alcohol using a procedure similar to that described for compound 13a. The Mp was approximately 100-102° C., and the yield was approximately 14.6% by weight after recrystallization from ethanol. 1H NMR (acetone-d6): δ 8.2, 8.0 and 7.7 (3H, 2d, s, aromatic H), 5.8 (2H, d, ArCH2), 3.6-4.1 (4H, m, CH2CH2Cl), 3.5 and 3.2 (6H, 2s, 2 CH3SO2).

WORKUP

后处理

  1. customThe Mp was approximately 100-102° C., and the yield was approximately 14.6% by weight after recrystallization from ethanol