p-Toluenesulfonic acid → 1-Ethoxycyclohexene

HRID 1637562Notes

Reaction equation

HRID 1637562 reaction equation
C1(C)C=CC(S(O)(=O)=O)=CC=1.[CH2:12]([O:14][C:15]1(OCC)[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1)[CH3:13]>>[CH2:12]([O:14][C:15]1[CH2:20][CH2:19][CH2:18][CH2:17][CH:16]=1)[CH3:13]

Participants

3

Reactant 2

HCID 6101p-Toluenesulfonic acidHCID 74279Cyclohexane, 1,1-diethoxy-

Product 1

HCID 2248441-Ethoxycyclohexene

Procedure

The synthesis was the same as in Example 1 except that about 50 mg of p-toluene sulfonic acid and 50 ml diethoxycyclohexane (from Lancaster) were employed. Under vacuum overnight at about 90° C., some small amount of distilled liquid was discarded, then the temperature was raised up to 120°-130° C. and the 1-ethoxycyclohexene was collected through distillation.

Workup

  1. customUnder vacuum overnight
  2. customat about 90° C.
  3. temperaturethe temperature was raised up to 120°-130° C.
  4. distillationthe 1-ethoxycyclohexene was collected through distillation

Sources & evidence

ORD record
ord-806f0583709846ea9dac9d471de308b8
Source dataset
uspto-grants-2000_03
Patent number
US06043003

Reaction notes

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