Oxalic Acid → HCID 69408108, compound

HRID 1637563Notes

Reaction equation

HRID 1637563 reaction equation
C[CH:2]([O:6][C:7]([CH3:9])=[O:8])COC.[C:10]([O-])(=O)C(C)=C.[OH:16][CH:17]=[CH:18][C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1.C(O)(=O)C(O)=O>>[CH3:2][O:6][C:7](=[O:8])[CH:9]=[CH2:10].[OH:16][CH:17]=[CH:18][C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1

Participants

4

Reactant 3

HCID 971Oxalic AcidHCID 7946Propylene glycol methyl ether acetateHCID 131721739HCID 131721739, compound

Product 1

HCID 69408108HCID 69408108, compound

Procedure

The same procedure as described in Example 3 was employed in this example. Specifically, about 100 g of PGMEA solution containing 25 wt. percent of methacrylate-hydroxystyrene copolymer (CMM, 50/50, from Maruzen) was added in with about 35 mg of oxalic acid and 11.4 g of MOCH. The reaction was quenched with 4 g of basic active aluminum oxide and showed 41 mole % protection on the phenol groups of the PHS polymer.

Workup

  1. customThe reaction was quenched with 4 g of basic active aluminum oxide

Sources & evidence

ORD record
ord-66aacd979dd04a96afacda2d9a2ac2d3
Source dataset
uspto-grants-2000_03
Patent number
US06043003

Reaction notes

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