Phosphorus pentachloride → HCID 54329084, compound

HRID 1637959Notes

Reaction equation

HRID 1637959 reaction equation
[C:1]([N:4]1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[C:6](=[C:13](O)[C:14]2[CH:19]=[CH:18][C:17]([Br:20])=[CH:16][CH:15]=2)[C:5]1=[O:22])(=[O:3])[CH3:2].P(Cl)(Cl)(Cl)(Cl)[Cl:24]>C1(C)C=CC=CC=1>[C:1]([N:4]1[C:12]2[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=2)[C:6](=[C:13]([Cl:24])[C:14]2[CH:19]=[CH:18][C:17]([Br:20])=[CH:16][CH:15]=2)[C:5]1=[O:22])(=[O:3])[CH3:2]

Participants

4

Reactant 2

HCID 24819Phosphorus pentachlorideHCID 178473958HCID 178473958, compound

Product 1

HCID 54329084HCID 54329084, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

1-acetyl-3-[1-hydroxy-1-(4-bromo-phenyl)methylidene}-2-indolinone and 2 equivalents of PCl5 are heated in toluene for 1 hour at 100° C. The mixture is filtered, evaporated down in vacuo and petroleum ether is added to the oily evaporation residue.

Workup

  1. filtrationThe mixture is filtered
  2. customevaporated down in vacuo and petroleum ether
  3. additionis added to the oily evaporation residue

Sources & evidence

ORD record
ord-c8877ee150da4083996e89778e8313c8
Source dataset
uspto-grants-2000_03
Patent number
US06043254

Reaction notes

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