1-Chloro-2,4-Dinitrobenzene → HCID 18546600, compound

HRID 1638117Notes

Reaction equation

HRID 1638117 reaction equation
[OH:1][CH2:2][C:3]([F:42])([F:41])[C:4]([F:40])([F:39])[C:5]([F:38])([F:37])[C:6]([F:36])([F:35])[C:7]([F:34])([F:33])[C:8]([F:32])([F:31])[C:9]([F:30])([F:29])[C:10]([F:28])([F:27])[CH2:11][O:12][C:13]1[CH:26]=[CH:25][C:16]([C:17]([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)=[O:18])=[CH:15][CH:14]=1.[N+:43]([C:46]1[CH:51]=[C:50]([N+:52]([O-:54])=[O:53])[CH:49]=[CH:48][C:47]=1Cl)([O-:45])=[O:44]>CN1C(=O)CCC1>[N+:43]([C:46]1[CH:51]=[C:50]([N+:52]([O-:54])=[O:53])[CH:49]=[CH:48][C:47]=1[O:1][CH2:2][C:3]([F:41])([F:42])[C:4]([F:39])([F:40])[C:5]([F:37])([F:38])[C:6]([F:35])([F:36])[C:7]([F:33])([F:34])[C:8]([F:31])([F:32])[C:9]([F:29])([F:30])[C:10]([F:28])([F:27])[CH2:11][O:12][C:13]1[CH:26]=[CH:25][C:16]([C:17]([C:19]2[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=2)=[O:18])=[CH:15][CH:14]=1)([O-:45])=[O:44]

Participants

4

Reactant 2

HCID 61-Chloro-2,4-DinitrobenzeneHCID 18546622HCID 18546622, compound

Product 1

HCID 18546600HCID 18546600, compound

Reagents, catalysts & solvents 1

HCID 13387N-methyl-2-pyrrolidoneSolvent

Procedure

A solution of 4-(10-Hydroxy-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyloxy)benzophenone (6.42 g), 2,4-dinitrochlorobenzene (2.42 g) potassium carbonate (2.76 g) and NMP (15 mL) is heated to 75-80° C. for 24 hrs. The solution is further processed as described in Example 2 to give 4-[10-(2,4-dinitrophenoxy)-2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9-hexadecafluorodecyloxy]benzophenone.

Sources & evidence

ORD record
ord-ae7305fd8ab54e9f890df95166dc1946
Source dataset
uspto-grants-2000_03
Patent number
US06043337

Reaction notes

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