HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,1,3,3-Tetramethyldisilazane, 97% → HCID 59227480, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,1,3,3-Tetramethyldisilazane, 97% | HCID 85196 | — |
| Reactant | 3-(Cyclohex-1-en-1-yl)prop-2-yn-1-ol | HCID 12770182 | — |
| Product | HCID 59227480 | HCID 59227480 | 176% |
Reaction Steps
3-Cyclohexenylprop-2-yn-1-ol (2.509 g, 26.10 mmol) and 1,1,3,3-tetramethyldisilazane (1.527 g, 11.45 mmol) were used according to the method mentioned above to produce the title compound as a brown clear liquid (3.916 g, 20.15 mmol, 77.2%). The crude reaction mixture was analyzed by 1H NMR to confirm the product formation and used in KOtBu catalyzed transhydrosilylation reaction.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08110695B2 |
| Source dataset | uspto-grants-2012_02 |
| ORD ID | ord-dc702f953bd54bcdb9d2ccfc24939a18 |
| Source note | uspto-grants-2012_02 |