Propane, 2,2',2''-[methylidynetris(oxy)]tris- → Isopropyl 2-isopropoxymethylene-4,4,4-trifluoro-3-oxobutyrate

HRID 1641471Notes

Reaction equation

HRID 1641471 reaction equation
[F:1][C:2]([F:13])([F:12])[C:3](=[O:11])[CH2:4][C:5]([O:7][CH:8]([CH3:10])[CH3:9])=[O:6].[CH:14](OC(C)C)(OC(C)C)[O:15][CH:16]([CH3:18])[CH3:17]>>[CH:16]([O:15][CH:14]=[C:4]([C:3](=[O:11])[C:2]([F:12])([F:13])[F:1])[C:5]([O:7][CH:8]([CH3:10])[CH3:9])=[O:6])([CH3:18])[CH3:17]

Participants

3

Reactant 2

HCID 78191Propane, 2,2',2''-[methylidynetris(oxy)]tris-HCID 586897Isopropyl 4,4,4-Trifluoroacetoacetate

Product 1

HCID 86640097Isopropyl 2-isopropoxymethylene-4,4,4-trifluoro-3-oxobutyrate

Procedure

The preparation was carried out analogously to preparation example 1 using isopropyl 4,4,4-trifluoro-3-oxobutyrate and triisopropyl orthoformate.

Sources & evidence

ORD record
ord-0f1ae0b791d247e8a5ebbbd41c4dbad9
Source dataset
uspto-grants-2012_02
Patent number
US08115012B2

Reaction notes

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