Potassium Cation → 6-cyano-2,2-dimethyl-4-(4-ethoxycarbonyl-1,2-dihydro-2-oxo-1-pyridinyl)-2H-benzo[b]pyran

HRID 164186Notes

Reaction equation

HRID 164186 reaction equation
[CH3:1][S:2]([O:3][CH2:4][CH:7]1[CH:8]([n:21]2[c:22](=[O:32])[cH:23][c:24]([C:27](=[O:28])[O:29][CH2:30][CH3:31])[cH:25][cH:26]2)[c:9]2[c:10]([cH:15][cH:16][c:17]([C:19]#[N:20])[cH:18]2)[O:11][C:12]1([CH3:13])[CH3:14])(=[O:5])=[O:6].[CH3:33][C:34]([CH3:35])([O-:36])[CH3:37].[K+:38].[O:39]1[CH2:40][CH2:41][CH2:42][CH2:43]1>>[CH:7]1=[C:8]([n:21]2[c:22](=[O:32])[cH:23][c:24]([C:27](=[O:28])[O:29][CH2:30][CH3:31])[cH:25][cH:26]2)[c:9]2[c:10]([cH:15][cH:16][c:17]([C:19]#[N:20])[cH:18]2)[O:11][C:12]1([CH3:13])[CH3:14]

Participants

5

Reactant 4

HCID 813Potassium CationHCID 8028TetrahydrofuranHCID 45749132-Methylpropan-2-olateHCID 19092522Ethyl 1-[6-cyano-2,2-dimethyl-3-(methylsulfonyloxymethyl)-3,4-dihydrochromen-4-yl]-2-oxopyridine-4-carboxylate

Product 1

HCID 190925696-cyano-2,2-dimethyl-4-(4-ethoxycarbonyl-1,2-dihydro-2-oxo-1-pyridinyl)-2H-benzo[b]pyran

Sources & evidence

ORD record
ord-09002c93988e4e34a943fcd612187232
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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