Oxygen → Potassium Persulfate
Reaction equation
[OH:1][O:2][S:3]([O-:5])=[O:4].[K+:6].[O:7]=O.[OH:9][S:10]([O-])(=[O:12])=[O:11].[K+]>O>[S:3]([O:2][O:1][S:10]([O-:12])(=[O:11])=[O:9])([O-:7])(=[O:5])=[O:4].[K+:6].[K+:6]Participants
Reactant 3
Product 1
Reagents, catalysts & solvents 1
Procedure
Comparative Example A was prepared as for the “Conventional Complete Solution” described in Table 2 of Example 1 of U.S. Pat. No. 6,818,142. A 11.2% potassium monopersulfate solution was prepared by dissolving OXONE (12.6 g) potassium monopersulfate in deionized water (100 g) at a temperature of 22° C. The OXONE was mixed until completely dissolved. The resulting solution produced was prepared below the saturation limit expressed in Table 1 above. The resulting solution contained 0.51% active oxygen, 5.00% KHSO5, 2.54% KHSO4, pH=1.2, 10.56% total dissolved solids (TDS), and a 0.15:1 weight ratio of AO/SO4. A rate constant was derived from the data in Table 2 of U.S. Pat. No. 6,818,142 and found to be k=0.0062. Using Equation 1 above, the value of t10% was 17 days, where t10% is the time it takes to loose 10% of the active oxygen.
Workup
- customComparative Example A was prepared as for the “Conventional Complete Solution”
- dissolutionuntil completely dissolved
- customThe resulting solution produced
- customwas prepared below the saturation limit
- dissolutiondissolved solids (TDS)
Sources & evidence
- ORD record
- ord-57a7734bb6614287a819defd6ad23b6b
- Source dataset
- uspto-grants-2012_02
- Patent number
- US08123970B2
Reaction notes
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